Hydrogen evolution at liquid-liquid interfaces.
نویسندگان
چکیده
Blowing bubbles: Hydrogen evolution by proton reduction with [(C(5)Me(5))(2)Fe] occurs at a soft interface between water and 1,2-dichloroethane (DCE). The reaction proceeds by proton transfer assisted by [(C(5)Me(5))(2)Fe] across the water-DCE interface with subsequent proton reduction in DCE. The interface essentially acts as a proton pump, allowing hydrogen evolution by directly using the aqueous proton.
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ورودعنوان ژورنال:
- Angewandte Chemie
دوره 48 28 شماره
صفحات -
تاریخ انتشار 2009